33 research outputs found

    A preliminary systems-engineering study of an advanced nuclear-electrolytic hydrogen-production facility

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    An advanced nuclear-electrolytic hydrogen-production facility concept was synthesized at a conceptual level with the objective of minimizing estimated hydrogen-production costs. The concept is a closely-integrated, fully-dedicated (only hydrogen energy is produced) system whose components and subsystems are predicted on ''1985 technology.'' The principal components are: (1) a high-temperature gas-cooled reactor (HTGR) operating a helium-Brayton/ammonia-Rankine binary cycle with a helium reactor-core exit temperature of 980 C, (2) acyclic d-c generators, (3) high-pressure, high-current-density electrolyzers based on solid-polymer electrolyte technology. Based on an assumed 3,000 MWt HTGR the facility is capable of producing 8.7 million std cu m/day of hydrogen at pipeline conditions, 6,900 kPa. Coproduct oxygen is also available at pipeline conditions at one-half this volume. It has further been shown that the incorporation of advanced technology provides an overall efficiency of about 43 percent, as compared with 25 percent for a contemporary nuclear-electric plant powering close-coupled contemporary industrial electrolyzers

    The FIELDS Instrument Suite for Solar Probe Plus

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    Nonlinear Active Materials: An Illustration of Controllable Phase Matchability

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    For a crystal to exhibit nonlinear optical (NLO) activity such as second-harmonic generation (SHG), it must belong to a noncentrosymmetric (NCS) space group. Moreover, for these nonlinear optical (NLO) materials to be suitable for practical uses, the synthesized crystals should be phase-matchable (PM). Previous synthetic research into SHG-active crystals has centered on (i) how to create NCS compounds and/or (ii) how to obtain NCS compounds with high SHG efficiencies. With these tactics, one can synthesize a material with a high SHG efficiency, but the material could be unusable if the material was nonphase-matchable (non-PM). To probe the origin of phase matchability of NCS structures, we present two new chemically similar hybrid compounds within one composition space: <b>(I) </b>[Hdpa]<sub>2</sub>NbOF<sub>5</sub>·2H<sub>2</sub>O and <b>(II)</b> HdpaNbOF<sub>4</sub> (dpa = 2,2′-dipyridylamine). Both compounds are NCS and chemically similar, but <b>(I)</b> is non-PM while <b>(II)</b> is PM. Our results indicateconsistent with organic crystallographythe arrangement of the organic molecule within hybrid materials dictates whether the material is PM or non-PM

    Nonlinear Active Materials: An Illustration of Controllable Phase Matchability

    No full text
    For a crystal to exhibit nonlinear optical (NLO) activity such as second-harmonic generation (SHG), it must belong to a noncentrosymmetric (NCS) space group. Moreover, for these nonlinear optical (NLO) materials to be suitable for practical uses, the synthesized crystals should be phase-matchable (PM). Previous synthetic research into SHG-active crystals has centered on (i) how to create NCS compounds and/or (ii) how to obtain NCS compounds with high SHG efficiencies. With these tactics, one can synthesize a material with a high SHG efficiency, but the material could be unusable if the material was nonphase-matchable (non-PM). To probe the origin of phase matchability of NCS structures, we present two new chemically similar hybrid compounds within one composition space: <b>(I) </b>[Hdpa]<sub>2</sub>NbOF<sub>5</sub>·2H<sub>2</sub>O and <b>(II)</b> HdpaNbOF<sub>4</sub> (dpa = 2,2′-dipyridylamine). Both compounds are NCS and chemically similar, but <b>(I)</b> is non-PM while <b>(II)</b> is PM. Our results indicateconsistent with organic crystallographythe arrangement of the organic molecule within hybrid materials dictates whether the material is PM or non-PM
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